Product ID:1,1,1 TRICHLORETHANE TECHNICAL
MSDS Date:12/30/1986
FSC:6810
NIIN:00-664-0388
MSDS Number: BKBDJ

CSD, INC

# 5 HACKENBERRY
CONROE, TX 77305
US

Emergency Phone: 704-821-9822

Info Phone: 704-821-9822

Cage: 0LWP6

CSD, INC

687 CONROE, TX 77305 US

Telephone: 800-424-9300

Cage: 0LWP6

METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III) *

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 90-95%

OSHA PEL 350 PPM/450 STEL *

ACGIH TLV: 350 PPM/450STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

Health Hazards Acute and Chronic:OVEREXPOSURE CAN CAUSE VOMITING,
NAUSEA, DROWSINESS, UNCONSCIOUSNESS AND IN EXTREME CASES DEATH.
Explanation of Carcinogenicity:1,4-DIOXANE IS LISTED BY NTP AND IARC AS
AN ANIMAL CARCINOGEN 11,4-D
Effects of Overexposure:OVEREXPOSURE CAN CAUSE VOMITING, NAUSEA,
DROWSINESS, UNCONSCIOUSNESS AND IN EXTREME CASES DEATH.

First Aid:MOVE TO FRESH AIR. REMOVE CONTAMINATED CLOTHING. IF BREATHING
HAS STOPPED, ADMINISTER ARTIFICIAL RESPIRATION. KEEP WARM AND
QUIET. CALL PHYSICIAN. EYE CONTACT:WASH WITH COPIOUS AMOUNTS OF
WATER. NEVER ADMINISTER ADRENALINE.

Lower Limits:6.3
Upper Limits:15.5
Fire Fighting Procedures:SELF CONTAINED BREATHING EQUIPMENT SHOULD BE
USED BY FIREMEN IN BUILDING WHERE 1,1,1,TRICHLOREOTHANE IS STORED.
KEEP CONTAINER COOL.
Unusual Fire/Explosion Hazard:VAPORS CAN BE IGNITED BY HIGH ENERGY
IGNITION SOURCE. DECOMPOSES WITH FIRE OR HOT SURFACES TO ACIDIC
GASES & OTHER HIGHLY TOXIC SUBSTANCE.

Spill Release Procedures:EVACUATE THE AREA, VENTILATE, AVOID BREATHING
VAPOR OR COMING IN CONTACT WITH LIQUID. CLEAN UP AREA (WEAR
PROTECTIVE CLOTHING) CONTAIN SPILL, TRANSFER BY MOPPING OR WITH
ABSORBENT MATERIAL TO STORAGE CONTAINER.

Handling and Storage Precautions:AVOID CONTACT WITH SKIN AND VAPORS.
PIPE VENTS OUTDOORS, STORE IN COOL DRY VENTILATED AREA.
Other Precautions:PREVENT MOIST AIR FROM ENTERING STORAGE. NO SMOKING
IN PRESENCE OF VAPORS.

Respiratory Protection:NONE REQUIRED WITH ADEQUATE VENTILATION.
Ventilation:LOCAL EXHAUST SUFFICIENT TO MAINTAIN BELOW TLV.
Protective Gloves:USE NEOPRENE, VITRON, OR P.V.C. COATED.
Eye Protection:SAFETY GOGGLES
Other Protective Equipment:PROTECTIVE HEADGEAR AND APRON WHEN SPLASHING
IS A PROBLEM.
Supplemental Safety and Health
INGREDIENT 2 ADDED BY HMIS (DGSC) TECHNICIAN AFTER CONVERSTION WITH MR.
STEVE COOK; SAFETY FOR CSD, INC. FIELD QUESTIONED COMPOSITITON- 1,4
DIOXANE HAD BEEN LEFT OFF AFTER LAST UPDATE.

HCC:T4
Boiling Pt:B.P. Text:162F,72C
Melt/Freeze Pt:M.P/F.P Text:-36F,-38C
Vapor Pres:100
Vapor Density:4.6
Spec Gravity:1.3
Viscosity:0.86
Evaporation Rate & Reference:0.4 (ETHER=1)
Solubility in Water:MODERATE
Appearance and Odor:COLORLESS CLEAR LIQUID, MILDLY SWEET ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:CONTACT WITH OPEN FLAME, HOT SURFACES OR
EMISSION FROM WELDING ARC.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, PHOSGENE AND OTHER
HIGHLY TOXIC SUBSTANCES.

Waste Disposal Methods:CONSULT MANUFACTURER OR LOCAL POLLUTION CONTROL
AGENCY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.